Wheel-shaped ErIIIZnII3 single-molecule magnet: A macrocyclic approach to designing magnetic anisotropy

Aika Yamashita, Akiko Watanabe, Shigehisa Akine, Tatsuya Nabeshima, Motohiro Nakano, Tomoo Yamamura, Takashi Kajiwara

研究成果: Article

174 引用 (Scopus)

抜粋

Designer SMM: An ErIII-based single-molecule magnet (SMM) was synthesized by designing the ligand-field anisotropy around an ErIII ion in an equatorial arrangement of donors using a rigid and planar macrocyclic Schiff base ligand including three ZnII ions. The resulting Er IIIZnII3 complex (see picture; C gray, O red, N blue) behaves as a SMM with an energy barrier of 24.6(9) K for flipping of the molecular magnetic moment.

元の言語English
ページ(範囲)4016-4019
ページ数4
ジャーナルAngewandte Chemie - International Edition
50
発行部数17
DOI
出版物ステータスPublished - 2011 4 18

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

フィンガープリント Wheel-shaped Er<sup>III</sup>Zn<sup>II</sup><sub>3</sub> single-molecule magnet: A macrocyclic approach to designing magnetic anisotropy' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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    Yamashita, A., Watanabe, A., Akine, S., Nabeshima, T., Nakano, M., Yamamura, T., & Kajiwara, T. (2011). Wheel-shaped ErIIIZnII3 single-molecule magnet: A macrocyclic approach to designing magnetic anisotropy. Angewandte Chemie - International Edition, 50(17), 4016-4019. https://doi.org/10.1002/anie.201008180