抄録
Designer SMM: An ErIII-based single-molecule magnet (SMM) was synthesized by designing the ligand-field anisotropy around an ErIII ion in an equatorial arrangement of donors using a rigid and planar macrocyclic Schiff base ligand including three ZnII ions. The resulting Er IIIZnII3 complex (see picture; C gray, O red, N blue) behaves as a SMM with an energy barrier of 24.6(9) K for flipping of the molecular magnetic moment.
本文言語 | English |
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ページ(範囲) | 4016-4019 |
ページ数 | 4 |
ジャーナル | Angewandte Chemie - International Edition |
巻 | 50 |
号 | 17 |
DOI | |
出版ステータス | Published - 2011 4月 18 |
ASJC Scopus subject areas
- 触媒
- 化学 (全般)