Wheel-shaped ErIIIZnII3 single-molecule magnet: A macrocyclic approach to designing magnetic anisotropy

Aika Yamashita, Akiko Watanabe, Shigehisa Akine, Tatsuya Nabeshima, Motohiro Nakano, Tomoo Yamamura, Takashi Kajiwara

研究成果: Article査読

191 被引用数 (Scopus)

抄録

Designer SMM: An ErIII-based single-molecule magnet (SMM) was synthesized by designing the ligand-field anisotropy around an ErIII ion in an equatorial arrangement of donors using a rigid and planar macrocyclic Schiff base ligand including three ZnII ions. The resulting Er IIIZnII3 complex (see picture; C gray, O red, N blue) behaves as a SMM with an energy barrier of 24.6(9) K for flipping of the molecular magnetic moment.

本文言語English
ページ(範囲)4016-4019
ページ数4
ジャーナルAngewandte Chemie - International Edition
50
17
DOI
出版ステータスPublished - 2011 4月 18

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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