Water-vapor-induced reversible switching of electronic states in an MMX-type chain complex with retention of single crystallinity

Hiroaki Iguchi; Shinya Takaishi; Hitoshi Miyasaka; Masahiro Yamashita; Hiroyuki Matsuzaki; Hiroshi Okamoto; Hisaaki Tanaka; Shin Ichi Kuroda

doi:10.1002/anie.200905608

Water-vapor-induced reversible switching of electronic states in an MMX-type chain complex with retention of single crystallinity

Hiroaki Iguchi, Shinya Takaishi, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, Shin Ichi Kuroda

研究成果: Article › 査読

24 被引用数 (Scopus)

抄録

(Figure Presented) Back and forth: Reversible structural change and changes in the physical properties of a quasi-1 D dinuclear Pt complex occurred with dehydration and rehydration. Upon dehydration, the electronic state changed from an alternating charge-polarization and charge-density-wave (ACP + CDW) state to a narrow-gapped CDW state with an increase in the electrical conductivity and molar spin susceptibility at room temperature.

本文言語	English
ページ（範囲）	552-555
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	49
号	3
DOI	https://doi.org/10.1002/anie.200905608
出版ステータス	Published - 2010 1月 12

ASJC Scopus subject areas

触媒
化学 (全般)

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10.1002/anie.200905608

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引用スタイル

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abstract = "(Figure Presented) Back and forth: Reversible structural change and changes in the physical properties of a quasi-1 D dinuclear Pt complex occurred with dehydration and rehydration. Upon dehydration, the electronic state changed from an alternating charge-polarization and charge-density-wave (ACP + CDW) state to a narrow-gapped CDW state with an increase in the electrical conductivity and molar spin susceptibility at room temperature.",

keywords = "Chain structures, Electric conductors, Phase transitions, Platinum, Reversible dehydration",

author = "Hiroaki Iguchi and Shinya Takaishi and Hitoshi Miyasaka and Masahiro Yamashita and Hiroyuki Matsuzaki and Hiroshi Okamoto and Hisaaki Tanaka and Kuroda, {Shin Ichi}",

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doi = "10.1002/anie.200905608",

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AU - Iguchi, Hiroaki

AU - Takaishi, Shinya

AU - Miyasaka, Hitoshi

AU - Yamashita, Masahiro

AU - Matsuzaki, Hiroyuki

AU - Okamoto, Hiroshi

AU - Tanaka, Hisaaki

AU - Kuroda, Shin Ichi

PY - 2010/1/12

Y1 - 2010/1/12

N2 - (Figure Presented) Back and forth: Reversible structural change and changes in the physical properties of a quasi-1 D dinuclear Pt complex occurred with dehydration and rehydration. Upon dehydration, the electronic state changed from an alternating charge-polarization and charge-density-wave (ACP + CDW) state to a narrow-gapped CDW state with an increase in the electrical conductivity and molar spin susceptibility at room temperature.

AB - (Figure Presented) Back and forth: Reversible structural change and changes in the physical properties of a quasi-1 D dinuclear Pt complex occurred with dehydration and rehydration. Upon dehydration, the electronic state changed from an alternating charge-polarization and charge-density-wave (ACP + CDW) state to a narrow-gapped CDW state with an increase in the electrical conductivity and molar spin susceptibility at room temperature.

KW - Chain structures

KW - Electric conductors

KW - Phase transitions

KW - Platinum

KW - Reversible dehydration

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