Water-vapor-induced reversible switching of electronic states in an MMX-type chain complex with retention of single crystallinity

Hiroaki Iguchi, Shinya Takaishi, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, Shin Ichi Kuroda

研究成果: Article査読

24 被引用数 (Scopus)

抄録

(Figure Presented) Back and forth: Reversible structural change and changes in the physical properties of a quasi-1 D dinuclear Pt complex occurred with dehydration and rehydration. Upon dehydration, the electronic state changed from an alternating charge-polarization and charge-density-wave (ACP + CDW) state to a narrow-gapped CDW state with an increase in the electrical conductivity and molar spin susceptibility at room temperature.

本文言語English
ページ(範囲)552-555
ページ数4
ジャーナルAngewandte Chemie - International Edition
49
3
DOI
出版ステータスPublished - 2010 1月 12

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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