Visible to near-infrared ultrafast spectroscopy of a quasi-one-dimensional halogen-bridged mixed-valence metal complex [Pt(en)2][Pt(en)2Cl2](ClO4)4

Atsushi Sugita, Tomoshige Furuhi, Masahiro Yamashita, Takayoshi Kobayashi

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Ultrafast relaxation dynamics is studied in a quasi-one-dimensional halogen-bridged mixed-valence metal complex [Pt(en)2] [Pt(en)2Cl2](CIO4)4 by pump-probe spectroscopy. A photoinduced absorption spectrum is measured in a broadband energy region of 0.6-2.6 eV, applying optical parametric amplification. The measurement is performed at both 293 and 4 K. The photoinduced absorption spectrum consists of the three contributions with different time and temperature dependence. One is the absorption band ascribed to the self-trapped exciton (STE), and the second is that due to the spatially uncorrelated neutral-soliton pair. Just after the photoexcitation, the STE is in a nonequilibrium state, and the time required for the thermalization is evaluated to be about 1 ps. The formation time of the third one is coincident with the thermalization time of the STE, and it is attributed to the spatially confined neutral-soliton pair.

本文言語English
ページ(範囲)581-588
ページ数8
ジャーナルJournal of Physical Chemistry A
106
4
DOI
出版ステータスPublished - 2002 1月 31
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学

フィンガープリント

「Visible to near-infrared ultrafast spectroscopy of a quasi-one-dimensional halogen-bridged mixed-valence metal complex [Pt(en)2][Pt(en)2Cl2](ClO4)4 」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル