Utilization of chemical and structural characteristics of tetraaza cycloalkane complexes

Tasuku Ito, Masako Kato, Masahiro Yamashita, Haruko Ito

研究成果: Article査読

30 被引用数 (Scopus)

抄録

The research investigations aiming at taking advantage of the chemical and structural consequences of ligand macrocyclization are reviewed with regard to the three features as follows: (1) Tetraazacycloalkane complexes which take up carbon dioxide as ROCO2- or R2NCO2-: (2) Correlation between axial and in-plane coordination bond lengths in tetragonal six-coordinate complexes of the trans-MX2N4-type (M=Co3+. Ni2+, and Zn2+)-X-ray structural and ab initio MO studies and (3) Stabilization of high oxidation states of metal ions and its application to chemistry of one-dimensional halogen-bridged M2+-M4+ mixed valence complexes.

本文言語English
ページ(範囲)29-52
ページ数24
ジャーナルJournal of Coordination Chemistry
15
1
DOI
出版ステータスPublished - 1986 4月

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 材料化学

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