Unusual chemoselective addition of diisopropylzinc to 2,2′-bipyridine-5,5′-dicarbonyl compounds in the 2-position and autoxidative reconversion with carbon-carbon bond cleavage

Shigehisa Tanji, Takanori Shibata, Itaru Sato, Kenso Soai

研究成果: Article査読

5 被引用数 (Scopus)

抄録

The chemoselective addition of diisopropylzinc to 2,2′-bipyridine-5,5′-dicarbonyl compounds in the 2-position and autoxidative reconversion with carbon-carbon bond cleavage was presented. It was shown that i-Pr2Zn do not add to the aldehyde moiety but to the 2-position of the bipyridine to afford possessing a quaternary carbon atom in a yield of 69%. It was found that the i-Pr2Zn does not add to the aldehyde but to the 2-position of the bipyridine ring by destroying the aromaticity of the pyridine ring.

本文言語English
ページ(範囲)217-218
ページ数2
ジャーナルJournal of the Chemical Society. Perkin Transactions 1
3
DOI
出版ステータスPublished - 2001 2 7

ASJC Scopus subject areas

  • 化学 (全般)

フィンガープリント

「Unusual chemoselective addition of diisopropylzinc to 2,2′-bipyridine-5,5′-dicarbonyl compounds in the 2-position and autoxidative reconversion with carbon-carbon bond cleavage」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル