Unexpected reversal of stereochemistry observed in the addition of methallyltrimethylsilane to a chiral α-keto imide

Sayaka Ishii, Katsuya Saito, Shigefumi Kuwahara, Masaru Enomoto

研究成果: Article査読

抄録

A Lewis acid-promoted nucleophilic addition of methallyltrimethylsilane to a chiral α-keto imide proceeded with stereoselectivity opposite to that predicted from Soai's report. The difference in the structure of α-keto imides between Soai's and our cases might have affected the diastereofacial selectivity.

本文言語English
ページ(範囲)488-492
ページ数5
ジャーナルBioscience, Biotechnology, and Biochemistry
85
3
DOI
出版ステータスPublished - 2021 2 24

ASJC Scopus subject areas

  • Biotechnology
  • Analytical Chemistry
  • Biochemistry
  • Applied Microbiology and Biotechnology
  • Molecular Biology
  • Organic Chemistry

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