Unbiased Rotational Motions of an Ellipsoidal Guest in a Tight Yet Pliable Host

Zhe Sun, Tatsuru Mio, Tomohiko Okada, Taisuke Matsuno, Sota Sato, Hirohiko Kono, Hiroyuki Isobe

研究成果: Article査読

12 被引用数 (Scopus)

抄録

In the design of machinery such as steel bearings, a fundamental understanding of material characteristics provides an indispensable basis for the design. Although hydrocarbon cycloarylenes have started to be used for providing unique supramolecular bearings with anomalous dynamic behaviors, their fundamental understanding is immature. A unique property of the cycloarylene host is now reported: the cyclic host is so pliable that it tracks the orientational changes of the ellipsoidal guest, that is, C 70 fullerene. Unique structures of the complex were revealed by spectroscopic and crystallographic analyses, and additional theoretical investigations deepened our understanding by revealing the structural changes associated with unbiased rotational motions.

本文言語English
ページ(範囲)2040-2044
ページ数5
ジャーナルAngewandte Chemie - International Edition
58
7
DOI
出版ステータスPublished - 2019 2月 11

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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