Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives via photochemical cycloaddition of dialkylsilylene

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Regioselective cycloaddition of dialkylsilylene upon irradiation at 440 nm converts azulene and guaiazulene to bicyclic [4]dendralene and heptafulvene derivatives, respectively. Significant σ-π interactions in the resulting new silacycles were suggested using UV-vis spectra and theoretical calculations. This journal is

本文言語English
ページ(範囲)10707-10709
ページ数3
ジャーナルChemical Communications
51
53
DOI
出版ステータスPublished - 2015 7 7

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

フィンガープリント 「Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives via photochemical cycloaddition of dialkylsilylene」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル