Total synthesis of the proposed structure of brevenal

Haruhiko Fuwa, Makoto Ebine, Makoto Sasaki

研究成果: Article査読

53 被引用数 (Scopus)

抄録

Total synthesis of the proposed structure of brevenal, a natural marine polycyclic ether product, has been accomplished. The synthesis features (i) convergent synthesis of the pentacyclic polyether skeleton using our developed Suzuki-Miyaura coupling strategy and (ii) construction of the multi-substituted dienal side chain by CuTC-mediated Stille reaction. Comparison of the NMR data of the synthetic compound with those reported for the natural product revealed that the proposed structure of brevenal needs to be revised.

本文言語English
ページ(範囲)9648-9650
ページ数3
ジャーナルJournal of the American Chemical Society
128
30
DOI
出版ステータスPublished - 2006 8 2

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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