@article{b44a8671b9ca47dd87810a0ecf773a47,
title = "Total synthesis of (-)-rhazinilam using 1,3-dipolar cycloaddition of optically active m{\"u}nchnone intermediate",
abstract = "A concise stereocontrolled total synthesis of (-)-rhazinilam was achieved by the regioselective 1,3-dipolar cycloaddition of a fully elaborated optically active m{\"u}nchnone intermediate prepared from d-aspartic acid dimethyl ester. The regiochemistry of the 1,3-dipolar cycloaddition of m{\"u}nchnone intermediate to various arylacetylenes was also investigated.",
keywords = "1,3-Dipolar cycloaddition, Alkaloids, M{\"u}nchnone, Total synthesis",
author = "Kenji Sugimoto and Yuta Miyakawa and Hidetoshi Tokuyama",
note = "Funding Information: This work was financially supported by the Cabinet Office, Government of Japan through its {\textquoteleft}Funding Program for Next Generation World-Leading Researchers {\textquoteright} ( LS008 ) and a Grant-in-aid for Scientific Research (A) ( 26253001 ), JSPS . Publisher Copyright: {\textcopyright} 2014 Elsevier Ltd. All rights reserved.",
year = "2015",
month = jun,
day = "3",
doi = "10.1016/j.tet.2014.12.018",
language = "English",
volume = "71",
pages = "3619--3624",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "22",
}