Time-resolved EPR observation of the short-lived excited triplet states of diamagnetic metallophthalocyanines in a rigid glassy matrix

Kimio Akiyama, Shozo Tero-Kubota, Yusaku Ikegami

研究成果: Article査読

19 被引用数 (Scopus)

抄録

Time-resolved EPR spectra were first observed for the lowest excited triplet state of metallophthalocyanines (MPc: M2Na, Mg, and Zn) in a rigid glassy matrix at 77 K. The zero-field splitting |D| parameters are smaller compared with those of metalloporphyrins. Introduction of the Zn atom to Pc induced drastic change in the intersystem crossing process, while the effect on the ZFS parameters was small.

本文言語English
ページ(範囲)65-67
ページ数3
ジャーナルChemical Physics Letters
185
1-2
DOI
出版ステータスPublished - 1991 10 11

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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