Three dimensional porous Hofmann clathrate [MIIPtII(CN)4] (M = Co, Ni) synthesized by using postsynthetic reductive elimination

Takuro Okamura, Bin Wu, Hiroaki Iguchi, Brian K. Breedlove, Masahiro Yamashita, Wataru Kosaka, Hitoshi Miyasaka, Shinya Takaishi

研究成果: Article査読

7 被引用数 (Scopus)

抄録

We synthesized cyano-bridged three dimensional metal-organic frameworks [MII(H2O)2PtIV(CN)4Br2]·n(H2O) (1: M = Co, 2: M = Ni) with an NbO type topology. Although 1 and 2 have no accessible pores, these MOFs were found to undergo reductive elimination of the axial bromides on the PtIV ions as well as removal of water molecules upon heating to form porous [MIIPtII(CN)4] (1′: M = Co, 2′: M = Ni) with retention of their crystallinity.

本文言語English
ページ(範囲)6512-6515
ページ数4
ジャーナルChemical Communications
53
48
DOI
出版ステータスPublished - 2017

ASJC Scopus subject areas

  • 触媒
  • 電子材料、光学材料、および磁性材料
  • セラミックおよび複合材料
  • 化学 (全般)
  • 表面、皮膜および薄膜
  • 金属および合金
  • 材料化学

フィンガープリント

「Three dimensional porous Hofmann clathrate [MIIPtII(CN)4] (M = Co, Ni) synthesized by using postsynthetic reductive elimination」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル