Thermal and photochemical reactions of a cationic rhenocene-acetonitrile adduct: The first C-H bond activation by rhenocene cation

Hiromi Tobita, Kiyonari Hashidzume, Kouji Endo, Hiroshi Ogino

研究成果: Article査読

1 被引用数 (Scopus)

抄録

A cationic rhenocene-acetonitrile adduct [Cp2Re(NCMe)](BF4) (2) reacted with an excess of benzene and thiophene under UV irradiation to give the C-H bond activation products [Cp2Re(H)Ph](BF4) (6) and [Cp2Re(H)(2-C4H3S)](BF4) (7) in high yields. Deprotonation of 6 proceeded by treatment with DBU to give phenylrhenocene Cp2RePh (8), while protonation of 8 with HBF4 regenerated 6.

本文言語English
ページ(範囲)X-3407
ジャーナルOrganometallics
17
16
DOI
出版ステータスPublished - 1998 8 3

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

フィンガープリント 「Thermal and photochemical reactions of a cationic rhenocene-acetonitrile adduct: The first C-H bond activation by rhenocene cation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル