Thermal and photochemical reactions of a cationic rhenocene-acetonitrile adduct: The first C-H bond activation by rhenocene cation

Hiromi Tobita; Kiyonari Hashidzume; Kouji Endo; Hiroshi Ogino

doi:10.1021/om980421d

Thermal and photochemical reactions of a cationic rhenocene-acetonitrile adduct: The first C-H bond activation by rhenocene cation

Hiromi Tobita, Kiyonari Hashidzume, Kouji Endo, Hiroshi Ogino

高度教養教育・学生支援機構（機構レベル所属のみ）

研究成果: Article › 査読

8 被引用数 (Scopus)

抄録

A cationic rhenocene-acetonitrile adduct [Cp₂Re(NCMe)](BF₄) (2) reacted with an excess of benzene and thiophene under UV irradiation to give the C-H bond activation products [Cp₂Re(H)Ph](BF₄) (6) and [Cp₂Re(H)(2-C₄H₃S)](BF₄) (7) in high yields. Deprotonation of 6 proceeded by treatment with DBU to give phenylrhenocene Cp₂RePh (8), while protonation of 8 with HBF₄ regenerated 6.

本文言語	English
ページ（範囲）	X-3407
ジャーナル	Organometallics
巻	17
号	16
DOI	https://doi.org/10.1021/om980421d
出版ステータス	Published - 1998 8月 3

ASJC Scopus subject areas

物理化学および理論化学
有機化学
無機化学

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10.1021/om980421d

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引用スタイル

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title = "Thermal and photochemical reactions of a cationic rhenocene-acetonitrile adduct: The first C-H bond activation by rhenocene cation",

abstract = "A cationic rhenocene-acetonitrile adduct [Cp2Re(NCMe)](BF4) (2) reacted with an excess of benzene and thiophene under UV irradiation to give the C-H bond activation products [Cp2Re(H)Ph](BF4) (6) and [Cp2Re(H)(2-C4H3S)](BF4) (7) in high yields. Deprotonation of 6 proceeded by treatment with DBU to give phenylrhenocene Cp2RePh (8), while protonation of 8 with HBF4 regenerated 6.",

author = "Hiromi Tobita and Kiyonari Hashidzume and Kouji Endo and Hiroshi Ogino",

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T2 - The first C-H bond activation by rhenocene cation

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AU - Endo, Kouji

AU - Ogino, Hiroshi

PY - 1998/8/3

Y1 - 1998/8/3

N2 - A cationic rhenocene-acetonitrile adduct [Cp2Re(NCMe)](BF4) (2) reacted with an excess of benzene and thiophene under UV irradiation to give the C-H bond activation products [Cp2Re(H)Ph](BF4) (6) and [Cp2Re(H)(2-C4H3S)](BF4) (7) in high yields. Deprotonation of 6 proceeded by treatment with DBU to give phenylrhenocene Cp2RePh (8), while protonation of 8 with HBF4 regenerated 6.

AB - A cationic rhenocene-acetonitrile adduct [Cp2Re(NCMe)](BF4) (2) reacted with an excess of benzene and thiophene under UV irradiation to give the C-H bond activation products [Cp2Re(H)Ph](BF4) (6) and [Cp2Re(H)(2-C4H3S)](BF4) (7) in high yields. Deprotonation of 6 proceeded by treatment with DBU to give phenylrhenocene Cp2RePh (8), while protonation of 8 with HBF4 regenerated 6.

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