TY - JOUR
T1 - The reaction of organozinc compounds with an aldehyde within a crystalline molecular flask
AU - Ikemoto, Koki
AU - Inokuma, Yasuhide
AU - Fujita, Makoto
PY - 2010/8/2
Y1 - 2010/8/2
N2 - (Figure Presented) Organozinc addition reactions were carried out on an aldehyde within a porous coordination network (see picture) in a single-crystal-to-single-crystal fashion, and the product structure was unambiguously determined by X-ray diffraction. Moreover, a one-pot two-step reaction in a single crystal furnished an ester from an aldehyde without the network losing crystallinity.
AB - (Figure Presented) Organozinc addition reactions were carried out on an aldehyde within a porous coordination network (see picture) in a single-crystal-to-single-crystal fashion, and the product structure was unambiguously determined by X-ray diffraction. Moreover, a one-pot two-step reaction in a single crystal furnished an ester from an aldehyde without the network losing crystallinity.
KW - Metal-organic frameworks
KW - Organozinc compounds
KW - Porous networks
KW - Single-crystal modifications
KW - X-ray diffraction
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U2 - 10.1002/anie.201002053
DO - 10.1002/anie.201002053
M3 - Article
C2 - 20629003
AN - SCOPUS:77955328679
VL - 49
SP - 5750
EP - 5752
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 33
ER -