The intra- and intermolecular Pauson-Khand reaction promoted by alkyl methyl sulfides

Takumichi Sugihara; Mamiko Yamada; Masahiko Yamaguchi; Mugio Nishizawa

doi:10.1055/s-1999-2745

The intra- and intermolecular Pauson-Khand reaction promoted by alkyl methyl sulfides

Takumichi Sugihara, Mamiko Yamada, Masahiko Yamaguchi, Mugio Nishizawa

薬学研究科・分子薬科学専攻

研究成果: Article › 査読

140 被引用数 (Scopus)

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The Pauson-Khand reaction was promoted by the addition of alkyl methyl sulfides. Among the sulfides, the ones having primary and secondary alkyl groups were more effective than those with tertiary alkyl groups. The intermolecular cyclization with simple alkenes makes the use of n-butyl methyl sulfide as the best method to carry out the stoichiometric Pauson- Khand reaction.

本文言語	English
ページ（範囲）	771-773
ページ数	3
ジャーナル	Synlett
号	6
DOI	https://doi.org/10.1055/s-1999-2745
出版ステータス	Published - 1999 1月 1

ASJC Scopus subject areas

有機化学

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10.1055/s-1999-2745

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abstract = "The Pauson-Khand reaction was promoted by the addition of alkyl methyl sulfides. Among the sulfides, the ones having primary and secondary alkyl groups were more effective than those with tertiary alkyl groups. The intermolecular cyclization with simple alkenes makes the use of n-butyl methyl sulfide as the best method to carry out the stoichiometric Pauson- Khand reaction.",

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author = "Takumichi Sugihara and Mamiko Yamada and Masahiko Yamaguchi and Mugio Nishizawa",

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AU - Nishizawa, Mugio

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N2 - The Pauson-Khand reaction was promoted by the addition of alkyl methyl sulfides. Among the sulfides, the ones having primary and secondary alkyl groups were more effective than those with tertiary alkyl groups. The intermolecular cyclization with simple alkenes makes the use of n-butyl methyl sulfide as the best method to carry out the stoichiometric Pauson- Khand reaction.

AB - The Pauson-Khand reaction was promoted by the addition of alkyl methyl sulfides. Among the sulfides, the ones having primary and secondary alkyl groups were more effective than those with tertiary alkyl groups. The intermolecular cyclization with simple alkenes makes the use of n-butyl methyl sulfide as the best method to carry out the stoichiometric Pauson- Khand reaction.

KW - Alkyne

KW - Carbonyl complexes

KW - Cobalt

KW - Cyclization

KW - Sulfide

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The intra- and intermolecular Pauson-Khand reaction promoted by alkyl methyl sulfides

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