The first observation of the [Cp3Mn]2 anion; structures of hexagonal [(η2-Cp)3MnK·1.5thf] and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6]·2thf

Yoshiharu Iwabuchi, Mariko Furukawa, Tomoyuki Esumi, Susumi Hatakeyama

研究成果: Article査読

144 被引用数 (Scopus)

抄録

A new enantiocontrolled synthesis of a potent immunosuppressant (2)-mycestericin E has been accomplished by using cinchona alkaloid-catalyzed asymmetric Baylis-Hillman reaction of an aldehyde with 1,1,1,3,3,3-hexafluoroisopropyl acrylate and Lewis acid-promoted cyclisation of an epoxytrichloroacetimidate as the key steps.

本文言語English
ページ(範囲)2030-2031
ページ数2
ジャーナルChemical Communications
1
19
DOI
出版ステータスPublished - 2001 1 1
外部発表はい

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

フィンガープリント 「The first observation of the [Cp3Mn]2 anion; structures of hexagonal [(η<sup>2</sup>-Cp)<sub>3</sub>MnK·1.5thf] and ion-separated [(η<sup>2</sup>-Cp)3Mn]<sub>2</sub>[Mg(thf)<sub>6</sub>]·2thf」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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