The first observation of the [Cp3Mn]2 anion; structures of hexagonal [(η2-Cp)3MnK·1.5thf] and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6]·2thf

Yoshiharu Iwabuchi; Mariko Furukawa; Tomoyuki Esumi; Susumi Hatakeyama

doi:10.1039/b106471c

The first observation of the [Cp3Mn]2 anion; structures of hexagonal [(η²-Cp)₃MnK·1.5thf] and ion-separated [(η²-Cp)3Mn]₂[Mg(thf)₆]·2thf

Yoshiharu Iwabuchi, Mariko Furukawa, Tomoyuki Esumi, Susumi Hatakeyama

研究成果: Article › 査読

148 被引用数 (Scopus)

抄録

A new enantiocontrolled synthesis of a potent immunosuppressant (2)-mycestericin E has been accomplished by using cinchona alkaloid-catalyzed asymmetric Baylis-Hillman reaction of an aldehyde with 1,1,1,3,3,3-hexafluoroisopropyl acrylate and Lewis acid-promoted cyclisation of an epoxytrichloroacetimidate as the key steps.

本文言語	English
ページ（範囲）	2030-2031
ページ数	2
ジャーナル	Chemical Communications
巻	1
号	19
DOI	https://doi.org/10.1039/b106471c
出版ステータス	Published - 2001 1月 1
外部発表	はい

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

文献へのアクセス

10.1039/b106471c

他のファイルとリンク

フィンガープリント

「The first observation of the [Cp3Mn]2 anion; structures of hexagonal [(η²-Cp)₃MnK·1.5thf] and ion-separated [(η²-Cp)3Mn]₂[Mg(thf)₆]·2thf」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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abstract = "A new enantiocontrolled synthesis of a potent immunosuppressant (2)-mycestericin E has been accomplished by using cinchona alkaloid-catalyzed asymmetric Baylis-Hillman reaction of an aldehyde with 1,1,1,3,3,3-hexafluoroisopropyl acrylate and Lewis acid-promoted cyclisation of an epoxytrichloroacetimidate as the key steps.",

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AU - Hatakeyama, Susumi

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