The chemistry of the processes involved in the production of lanthanide titanates by the polymerized-complex method

Dimitr S. Todorovsky, Miroslava M. Getsova, Maria M. Milanova, Masato Kakihana, Nikolina L. Petrova, Michali G. Arnaudov, Venelin G. Enchev

研究成果: Article査読

11 被引用数 (Scopus)

抄録

The composition, some spectral characteristics, and thermal decomposition of solid lanthanide-titanium (lanthanide (Ln) = Y, La, Ce) and lanthanide-titanium citrates (CA) and tartrates (TA) have been studied. The complexes have been prepared in ethylene glycol medium at conditions modeling those of the polymerized-complex method applied for Ln2Ti 2O7 preparation. Special attention has been paid to the chemical nature of the bimetallic products as well as to the factors influencing the deprotonation of the alcoholic OH groups of the acidic ligands. The results contribute to further elucidation of the complexation and thermal decomposition processes involved in the polymerizedcomplex method.

本文言語English
ページ(範囲)547-559
ページ数13
ジャーナルCanadian Journal of Chemistry
85
7-8
DOI
出版ステータスPublished - 2007 7月
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 有機化学

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