The Attacking Probability: A Factor Governing Replacement Reaction of Ruthenium Recoil Atoms in Solid Ruthenocene Derivative Complexes

Iwao Yamaguchi, Tsutomu Sekine, Hiroshi Kudo

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Replacement reactions of ruthenium recoil atoms have been examined with 97Ru and 103Ru recoil atoms produced by (γ,n) reactions in solid ruthenocene derivative complexes and their cyclodextrin inclusion compounds. The replacement reaction yields were inversely proportional to the square root of the average distance between two adjacent ruthenocene derivative molecules in solids. This relation was successfully explained by the replacement reaction model introducing the attacking probability; a probability of recoil atoms to attack the central atoms in ruthenocene derivative molecules through the geometrical open area of the sandwich structure.

本文言語English
ページ(範囲)69-74
ページ数6
ジャーナルRadiochimica Acta
77
1-2
DOI
出版ステータスPublished - 1997 1 1

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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