Synthetic study towards azadirachtin: An efficient and stereoselective construction of the AB rings with full functionality

Hidenori Watanabe, Naoki Mori, Daisuke Itoh, Takeshi Kitahara, Kenji Mori

研究成果: Article査読

31 被引用数 (Scopus)

抄録

(Chemical Equation Presented) From A to B: The decalin moiety of azadirachtin, which includes the fully functionalized AB ring system (see picture), was synthesized stereoselectively in only 23 steps. Key steps include an intramolecular Diels-Alder reaction, a decarboxylation, a Claisen rearrangement, and finally a tandem radical cyclization.

本文言語English
ページ(範囲)1512-1516
ページ数5
ジャーナルAngewandte Chemie - International Edition
46
9
DOI
出版ステータスPublished - 2007 6月 27
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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