Synthesis of the bicyclic [7.3.0] enediyne system of the maduropeptin chromophore: Remarkable atropisomerism of ansamacrolactam and isomerization of the C4-C13 double bond

Nobuki Kato, Satoshi Shimamura, Yoko Kikai, Masahiro Hirama

研究成果: Article

9 引用 (Scopus)

抜粋

A nine-membered diyne system of the maduropeptin chromophore was constructed for the first time using Nozaki-Hiyama-Kishi reaction. Unexpected atropisomerism of deoxyansamacrolactam and cis/trans isomerization of the exo-double bond of the chromophore were observed.

元の言語English
ページ(範囲)2107-2110
ページ数4
ジャーナルSynlett
発行部数12
DOI
出版物ステータスPublished - 2004 10 1

ASJC Scopus subject areas

  • Organic Chemistry

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