Synthesis of strained pyridine-containing cyclyne via reductive aromatization

Koji Miki, Michiyasu Fujita, Yuki Inoue, Yoshinori Senda, Toshiyuki Kowada, Kouichi Ohe

研究成果: Article査読

38 被引用数 (Scopus)

抄録

The Sonogashira-Hagihara coupling reactions of 2,6-diiodopyridine and cis-3,6-diethynyl-3,6-dimethoxycyclohexa-1,4-diene or cis-9,10-diethynyl-9,10- dimethoxy-9,10-dihydroanthracene gave macrocyclic compounds having alternating 2,6-diethynylpyridine and 3,6-dimethoxycyclohexa-1,4-diene segments. Transformation of the C3-symmetric 2,6-diethynylpyridine-based cyclotrimer was efficiently achieved using tin-mediated reductive aromatization under mild conditions.

本文言語English
ページ(範囲)3537-3540
ページ数4
ジャーナルJournal of Organic Chemistry
75
10
DOI
出版ステータスPublished - 2010 5 21
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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