Synthesis of homologous compounds Fe2O3(ZnO)m (m=6, 8, 34) by various selective microwave heating conditions

研究成果: Article査読

6 被引用数 (Scopus)


Homologous compounds, Fe2O3(ZnO)m, with a modulated natural superlattice structure, were synthesized within 10 min at 1200 °C in a simple solid-state reaction under 2.45 and 28 GHz microwave irradiation. Transmission electron microscopy and energy dispersive X-ray spectroscopy results revealed that m decreased with increasing the synthesis temperature and microwave frequency. In the Zn-Fe-O system, γ-Fe2O3 was heated in H and E-field and ZnO was heated in E-field under 2.45 GHz microwave irradiation. However, α, γ-Fe2O3 and calcined ZnO were heated under 28 GHz microwave irradiation. This selective microwave heating resulted in the different diffusion conditions than conventional heating; therefore, homologous compounds with low m values were rapidly synthesized at low temperature.

ジャーナルCeramics International
出版ステータスPublished - 2015 4 9

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

フィンガープリント 「Synthesis of homologous compounds Fe<sub>2</sub>O<sub>3</sub>(ZnO)<sub>m</sub> (m=6, 8, 34) by various selective microwave heating conditions」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。