Synthesis of crystalline molecular gyrotops and phenylene rotation inside the cage

Wataru Setaka, Kazuyuki Inoue, Sayaka Higa, Seiki Yoshigai, Hirohiko Kono, Kentaro Yamaguchi

研究成果: Article査読

38 被引用数 (Scopus)

抄録

Phenylene-bridged macrocage molecules were synthesized as molecular gyrotops because the rotor can rotate even in a crystal. The chain-length-dependent properties of the molecular gyrotops were investigated in order to explore the potential to create new molecular materials. The formation of the cage in the synthesis of each molecular gyrotop depended on the length of the alkyl chains of the precursor. The rotation modes and energy barriers for phenylene rotation inside the crystals of the molecular gyrotops were changed by varying the chain length of the cage.

本文言語English
ページ(範囲)8288-8295
ページ数8
ジャーナルJournal of Organic Chemistry
79
17
DOI
出版ステータスPublished - 2014 9月 5

ASJC Scopus subject areas

  • 有機化学

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