Synthesis of bulky phosphines by rhodium-catalyzed formal [2 + 2 + 2] cycloaddition reactions of tethered diynes with 1-alkynylphosphine sulfides

Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima

研究成果: Article

67 引用 (Scopus)

抜粋

The reaction of tethered diynes with 1-alkynylphosphine sulfides under rhodium catalysis provides the corresponding phosphine sulfides having a bulky aryl group. The following desulfidation yields bulky phosphines that will potentially serve as ligands in transition-metal-catalyzed reactions.

元の言語English
ページ(範囲)6996-6997
ページ数2
ジャーナルJournal of the American Chemical Society
129
発行部数22
DOI
出版物ステータスPublished - 2007 6 6
外部発表Yes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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