Synthesis of both enantiomers of a novel sesquiterpene isolated from the pheromone gland of a stink bug, Tynacantha marginata Dallas

Shigefumi Kuwahara, J. Ishikawa, W. S. Leal, S. Hamade, O. Kodama

    研究成果: Article査読

    19 被引用数 (Scopus)

    抄録

    Synthesis of both enantiomers of a novel sesquiterpene, isolated as the putative sex pheromone of a Brazilian predatory stink bug (Tynacantha matginata Dallas) and proposed to have an unprecedented tricyclic carbon framework, was accomplished through an intramolecular Diels-Alder cyclization of a single optically active triene intermediate and separation of a pair of structural isomers derived from the resulting cycloadducts.

    本文言語English
    ページ(範囲)1930-1935
    ページ数6
    ジャーナルSynthesis
    13
    DOI
    出版ステータスPublished - 2000 1月 1

    ASJC Scopus subject areas

    • 触媒
    • 有機化学

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