Synthesis and transformation of a novel methano[60]fullerene having a formyl group

Masahiro Hamada, Tetsuo Hino, Kazushi Kinbara, Kazuhiko Saigo

研究成果: Article査読

24 被引用数 (Scopus)

抄録

The reaction of [60]fullerene with a dimethylsulfonium α-formylalkylide gave a novel methano[60]fullerene having a formyl group at the bridge-head carbon. This 2,2-[60]fulleroalkanal was readily converted into a variety of N-aryl-2,2-[60]fulleroaldimines by condensation with aromatic amines; one of them showed efficient quenching of the fluorescence of the [60]fullerene core, due to a photoinduced intramolecular electron transfer.

本文言語English
ページ(範囲)5069-5071
ページ数3
ジャーナルTetrahedron Letters
42
30
DOI
出版ステータスPublished - 2001 7月 23

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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