Synthesis and structures of π-extended [n]Cyclo-para-phenylenes (n = 12, 16, 20) containing n/2 nitrogen atoms

Koki Ikemoto, Masahiro Fujita, Pei Chui Too, Ya Lin Tnay, Sota Sato, Shunsuke Chiba, Hiroyuki Isobe

    研究成果: Review article

    7 引用 (Scopus)

    抜粋

    [n]Cyclo-para-phenylene congeners of n = 12, 16, 20 with n/2 nitrogen atoms were synthesized via Pt-mediated one-pot macrocyclization reactions. The reaction allowed diversification of participating arylene numbers to afford a series of nanohoop molecules. Spectroscopic analyses in solution showed arylene rotations, and crystallographic analyses in crystals revealed an interesting packing motif. The nanohoop molecules were interwoven by the alkyl substituents in a thread-in-bead manner to form nanoporous packing structures in the crystal.

    元の言語English
    ページ(範囲)658-660
    ページ数3
    ジャーナルChemistry Letters
    45
    発行部数6
    DOI
    出版物ステータスPublished - 2016 1 1

    ASJC Scopus subject areas

    • Chemistry(all)

    フィンガープリント Synthesis and structures of π-extended [n]Cyclo-para-phenylenes (n = 12, 16, 20) containing n/2 nitrogen atoms' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Ikemoto, K., Fujita, M., Too, P. C., Tnay, Y. L., Sato, S., Chiba, S., & Isobe, H. (2016). Synthesis and structures of π-extended [n]Cyclo-para-phenylenes (n = 12, 16, 20) containing n/2 nitrogen atoms. Chemistry Letters, 45(6), 658-660. https://doi.org/10.1246/cl.160258