Synthesis and specific heat of CaPdH 3-δ with the perovskite structure

Shin Ya Ayukawa, Kazutaka Ikeda, Masatsune Kato, Takashi Noji, Shin Ichi Orimo, Yoji Koike

研究成果: Article

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Single-phase samples of the hydrogen-deficient perovskite hydride CaPdH 3-δ with δ = 0.9 have successfully been synthesized. First, a homogeneous alloy of CaPd was prepared through the hydrogenation and subsequent dehydrogenation of an inhomogeneous alloy of CaPd obtained through the induction melting of Ca and Pd metals. Next, CaPdH 3-δ with δ - 0.9 was synthesized through the hydrogenation of the homogeneous CaPd alloy at room temperature. No superconductivity has been observed above 2K in the magnetic-susceptibility measurements. The specific-heat measurements have revealed that there exist optical phonons due to hydrogen vibrations with the Einstein temperature as high as about 1000 K.

元の言語English
記事番号034704
ジャーナルjournal of the physical society of japan
81
発行部数3
DOI
出版物ステータスPublished - 2012 3

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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