Synthesis and search for equilibrium compositions of borates with the huntite structure

Valery I. Chani, Kiyoshi Shimamura, Keiji Inoue, Tsuguo Fukuda, Kazumasa Sugiyama

研究成果: Article査読

13 被引用数 (Scopus)

抄録

Using the Bi2O3-B2O3 solvent, single crystals of (Ho,Bi)(Al,Ga)3(BO3)4, (Yb,Bi)Al3(BO3)4:Nd3+, (Er,Bi)Al3(BO3)4:Cr3+ and (Er,Bi)Ga3(BO3)4:Cr3+ with the huntite structure have been grown by spontaneous crystallization from a flux. The achieved productivity of the melt (crystal/melt weight ratio) was 38 wt%. The crystal composition and distribution coefficients for different cation positions were studied and the dependence of the probability of congruent melting on crystal composition was discussed. X-ray powder diffraction analysis data for grown crystals are presented.

本文言語English
ページ(範囲)173-178
ページ数6
ジャーナルJournal of Crystal Growth
132
1-2
DOI
出版ステータスPublished - 1993 9 1

ASJC Scopus subject areas

  • 凝縮系物理学
  • 無機化学
  • 材料化学

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