Synthesis and reactivity of (phosphinoaklyl)silyl complexes

Masaaki Okazaki, Shin Ohshitanai, Masatoshi Iwata, Hiromi Tobita, Hiroshi Ogino

研究成果: Article査読

44 被引用数 (Scopus)

抄録

Silyl ancillary ligands are expected to generate the reactive unsaturated metal center due to their exceptionally strong trans-influence and -effect. Nevertheless, little has been known on the influence of silyl ligands on the reactivity of transition-metal complexes. This would be mainly due to the facile cleavage of the metal-silicon bond. (Phosphinoalkyl)silyl ligands have been developed to suppress the elimination of silyl groups from the metal center. This article reviews the synthesis and properties of the transition metal complexes having chelate-type (phosphinoalkyl)silyl ligands R2P(CH2)nSiR2 (n = 1, 2).

本文言語English
ページ(範囲)167-178
ページ数12
ジャーナルCoordination Chemistry Reviews
226
1-2
DOI
出版ステータスPublished - 2002

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

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