Synthesis and properties of transition-metal complexes coordinated with low-valent silicon and germanium

Hiromi Tobita, Hiroshi Ogino

研究成果: Article査読

3 被引用数 (Scopus)

抄録

Transition-metal complexes containing low-valent silicon and germanium ligands have attracted much attention because of their unique bonding modes as well as their possible intermediacy in various transformation reactions of organosilicon and -germanium compounds mediated by transition metals. This article describes (1) some reactions involving silylene and germylene complexes, in particular the fast intramolecular scrambling of substituents on the silicon atoms in silyl(silylene) iron complexes, and (2) the synthesis, structures, and properties of some new types of such complexes; namely, donor-stabilized bis(silylene), (silylene) (germylene), and bis(germylene) complexes.

本文言語English
ページ(範囲)530-570
ページ数41
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
53
6
DOI
出版ステータスPublished - 1995

ASJC Scopus subject areas

  • 有機化学

フィンガープリント

「Synthesis and properties of transition-metal complexes coordinated with low-valent silicon and germanium」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル