Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp*Rh{μ2-(NH)2C10H6-2,3}(μ2- Cl)RhCp*][PF6](Cp* = η5-C5Me5)

Hiroyuki Matsuzaka; Teruo Kamura; Ko Ariga; Takashi Okubo; Tomohiko Ishii; Masahiro Yamashita; Mitsuru Kondo; Susumu Kitagawa

doi:10.1080/10587250008038237

Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp^Rh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂- Cl)RhCp^][PF₆](Cp^* = η⁵-C₅Me₅)

Hiroyuki Matsuzaka, Teruo Kamura, Ko Ariga, Takashi Okubo, Tomohiko Ishii, Masahiro Yamashita, Mitsuru Kondo, Susumu Kitagawa

研究成果: Conference article › 査読

抄録

Reaction of [Cp^*RhCl₂]₂ (1) with (LiNH)₂C₁₀H₆-2,3 gives the mononuclear species Cp^*Rh(NH)₂C₁₀H₆-2,3 (3), which is selectively converted to the amido-bridged dinuclear Rh(III) complex [Cp^*Rh{μ₂-(NH)₂C₁₀H₆- 2,3}(μ₂-Cl)RhCp^*]PF₆ (4; Cp^* = η⁵-C₅Me₅) upon treatment with 1/AgPF₆ in acetone. The molecular structure of 4 has been determined by X-ray crystallography.

本文言語	English
ページ（範囲）	1-6
ページ数	6
ジャーナル	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
巻	342
DOI	https://doi.org/10.1080/10587250008038237
出版ステータス	Published - 2000
外部発表	はい
イベント	Proceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metal Complexes (AMS'99) - Kyoto, Jpn 継続期間: 1999 11月 30 → 1999 12月 2

ASJC Scopus subject areas

凝縮系物理学

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10.1080/10587250008038237

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「Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp^*Rh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂- Cl)RhCp^*][PF₆](Cp^* = η⁵-C₅Me₅)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

Matsuzaka, H., Kamura, T., Ariga, K., Okubo, T., Ishii, T., Yamashita, M., Kondo, M., & Kitagawa, S. (2000). Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp^*Rh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂- Cl)RhCp^*][PF₆](Cp^* = η⁵-C₅Me₅). Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 342, 1-6. https://doi.org/10.1080/10587250008038237

Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp^*Rh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂- Cl)RhCp^*][PF₆](Cp^* = η⁵-C₅Me₅). / Matsuzaka, Hiroyuki; Kamura, Teruo; Ariga, Ko その他.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 342, 2000, p. 1-6.

研究成果: Conference article › 査読

Matsuzaka, H, Kamura, T, Ariga, K, Okubo, T, Ishii, T, Yamashita, M, Kondo, M & Kitagawa, S 2000, 'Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp^*Rh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂- Cl)RhCp^*][PF₆](Cp^* = η⁵-C₅Me₅)', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 342, pp. 1-6. https://doi.org/10.1080/10587250008038237

Matsuzaka H, Kamura T, Ariga K, Okubo T, Ishii T, Yamashita M その他. Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp^*Rh{μ₂-(NH)₂C₁₀H₆-2,3}(μ₂- Cl)RhCp^*][PF₆](Cp^* = η⁵-C₅Me₅). Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 2000;342:1-6. doi: 10.1080/10587250008038237

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title = "Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp*Rh{μ2-(NH)2C10H6-2,3}(μ2- Cl)RhCp*][PF6](Cp* = η5-C5Me5)",

abstract = "Reaction of [Cp*RhCl2]2 (1) with (LiNH)2C10H6-2,3 gives the mononuclear species Cp*Rh(NH)2C10H6-2,3 (3), which is selectively converted to the amido-bridged dinuclear Rh(III) complex [Cp*Rh{μ2-(NH)2C10H6- 2,3}(μ2-Cl)RhCp*]PF6 (4; Cp* = η5-C5Me5) upon treatment with 1/AgPF6 in acetone. The molecular structure of 4 has been determined by X-ray crystallography.",

author = "Hiroyuki Matsuzaka and Teruo Kamura and Ko Ariga and Takashi Okubo and Tomohiko Ishii and Masahiro Yamashita and Mitsuru Kondo and Susumu Kitagawa",

note = "Funding Information: Acknowledgments This work was supported by the Grant-in-Aid for Scientific Research (No. 10640549, Pnority Areas No. 284-1 1190246 and 401-10149104) from The Ministry of Education, Science, Sports and Culture, Japan.; Proceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metal Complexes (AMS'99) ; Conference date: 30-11-1999 Through 02-12-1999",

year = "2000",

doi = "10.1080/10587250008038237",

language = "English",

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journal = "Molecular Crystals and Liquid Crystals",

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T1 - Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp*Rh{μ2-(NH)2C10H6-2,3}(μ2- Cl)RhCp*][PF6](Cp* = η5-C5Me5)

AU - Matsuzaka, Hiroyuki

AU - Kamura, Teruo

AU - Ariga, Ko

AU - Okubo, Takashi

AU - Ishii, Tomohiko

AU - Yamashita, Masahiro

AU - Kondo, Mitsuru

AU - Kitagawa, Susumu

N1 - Funding Information: Acknowledgments This work was supported by the Grant-in-Aid for Scientific Research (No. 10640549, Pnority Areas No. 284-1 1190246 and 401-10149104) from The Ministry of Education, Science, Sports and Culture, Japan.

PY - 2000

Y1 - 2000

N2 - Reaction of [Cp*RhCl2]2 (1) with (LiNH)2C10H6-2,3 gives the mononuclear species Cp*Rh(NH)2C10H6-2,3 (3), which is selectively converted to the amido-bridged dinuclear Rh(III) complex [Cp*Rh{μ2-(NH)2C10H6- 2,3}(μ2-Cl)RhCp*]PF6 (4; Cp* = η5-C5Me5) upon treatment with 1/AgPF6 in acetone. The molecular structure of 4 has been determined by X-ray crystallography.

AB - Reaction of [Cp*RhCl2]2 (1) with (LiNH)2C10H6-2,3 gives the mononuclear species Cp*Rh(NH)2C10H6-2,3 (3), which is selectively converted to the amido-bridged dinuclear Rh(III) complex [Cp*Rh{μ2-(NH)2C10H6- 2,3}(μ2-Cl)RhCp*]PF6 (4; Cp* = η5-C5Me5) upon treatment with 1/AgPF6 in acetone. The molecular structure of 4 has been determined by X-ray crystallography.

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