Synthesis and duplex formation of the reverse amidohelicene tetramer

Wataru Ichinose, Masamichi Miyagawa, Jun Ito, Masanori Shigeno, Ryo Amemiya, Masahiko Yamaguchi

研究成果: Article査読

11 被引用数 (Scopus)

抄録

The reverse amidohelicene (P)-tetramer containing (P)-helicenediamine and m-phenylenedicarboxylate was synthesized. The circular dichroism (CD) and vapor pressure osmometry (VPO) analysis revealed the dimeric aggregate formation in THF. It is notable that the reverse amide tetramer formed a duplex, as well as the original amidohelicene oligomers. In various solutions, mixtures of the reverse (P)-tetramer and amidohelicene (P)/(M)-tetramer formed homoaggregates instead of heteroaggregates.

本文言語English
ページ(範囲)5477-5486
ページ数10
ジャーナルTetrahedron
67
30
DOI
出版ステータスPublished - 2011 7 29

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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