Synthesis and double doping behavior of a poly(p-phenylenevinylene)s bearing conjugated side chains

Hirotsugu Kawashima, Kohsuke Kawabata, Hiromasa Goto

研究成果: Article査読

3 被引用数 (Scopus)

抄録

A poly(p-phenylenevinylene) derivative bearing conjugated side chains (polyCPV) was synthesized by Migita-Kosugi-Stille type coupling polycondensation reaction. This polymer contains phenylenevinylene units in both the main chain and the side chains. UV-vis absorption and fluorescence emission spectroscopies revealed a well-developed π-conjugation of the polyCPV. The absorption band of the polymer was extended to long wavelengths. A fluorescent emission maximum of polyCPV is located at considerably longer wavelengths than that of the conjugated side chain monomer. Electron spin resonance measurements of polyCPV confirmed generation of charge species in both the main chain and the side chains via iodine doping.

本文言語English
ページ(範囲)1530-1538
ページ数9
ジャーナルJournal of Polymer Science, Part A: Polymer Chemistry
50
8
DOI
出版ステータスPublished - 2012 4月 15
外部発表はい

ASJC Scopus subject areas

  • ポリマーおよびプラスチック
  • 有機化学
  • 材料化学

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