Synthesis and application of novel functional molecules by inner and outer control of fullerenyl cage focused on the spherical reaction sites

Hiroshi Ueno, Naohiko Ikuma, Ken Kokubo

研究成果: Article査読

抄録

Various types of functionalized fullerenes have been widely developed by considering unique reactivities of the spherical reaction sites; such as not only the enhanced reactivity due to the curved and thus strained C=C double bonds, but also the multiple addition and its electronic control for the selective monoaddition, the regioselectivity controls by spherical π-conjugation and by twisted C=C double bond, the unprecedented substitution mechanism, the highly symmetrical multiple addition via fullerene anion, and the drastic reactivity change by ion encapsulation. The derivatives also proved effective against many potential applications to CMP polishing slurry, antioxidant, anti-inflammatory agent, resist materials, n-type materials for organic photovoltaics, and more.

本文言語English
ページ(範囲)1348-1359
ページ数12
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
72
12
DOI
出版ステータスPublished - 2014 12 1
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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