Syntheses and odor descriptions of cyclopropanated compounds part 5. Analogs of methyl jasmonate to fix the relative configuration of the two side chains

Hiromasa Kiyota, Shin Ya Takigawa, Shigefumi Kuwahara

    研究成果: Article査読

    10 被引用数 (Scopus)

    抄録

    Analogs of methyl jasmonate (=methyl (1R*,2R*)-3-oxo-2-[(Z)- pent-2-enyl]cyclopentaneacetate; MJA) bearing a cyclopropane ring, double bond, or a F-substituent were synthesized, and their odor characteristics were examined. Most of the analogs with the same stereochemical properties as methyl epijasmonate showed odor properties superior to MJA. Interestingly, the enol acetate of MJA had a diffusive orchid-like note.

    本文言語English
    ページ(範囲)1854-1859
    ページ数6
    ジャーナルHelvetica Chimica Acta
    87
    7
    DOI
    出版ステータスPublished - 2004 8月 24

    ASJC Scopus subject areas

    • 触媒
    • 生化学
    • 創薬
    • 物理化学および理論化学
    • 有機化学
    • 無機化学

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