Synergetic effect in heterogeneous acid catalysis by a porous ionic crystal based on Al(iii)-salphen and polyoxometalate

Ryosuke Kawahara, Ryota Osuga, Junko N. Kondo, Noritaka Mizuno, Sayaka Uchida

研究成果: Article査読

7 被引用数 (Scopus)

抄録

A porous ionic crystal is synthesized with a cationic Al(iii)-salphen complex (Al(iii)-salphen) and a α-Keggin-type polyoxometalate (POM). The compound possesses stable three dimensional porous structure and shows high activity as a heterogeneous catalyst in pinacol rearrangement, which is a typical acid reaction. Notably, Al(iii)-salphen, POM, and a physical mixture of the two components are much less active, suggesting a synergetic effect of Al(iii)-salphen and POM in a porous framework.

本文言語English
ページ(範囲)3105-3109
ページ数5
ジャーナルDalton Transactions
46
10
DOI
出版ステータスPublished - 2017
外部発表はい

ASJC Scopus subject areas

  • 無機化学

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