TY - CHAP
T1 - Supramolecular nanostructures of phthalocyanines and porphyrins at surfaces based on the "bottom-up assembly"
AU - Yoshimoto, Soichiro
AU - Kobayashi, Nagao
N1 - Funding Information:
This work was supported in part by the JST program “Special Coordination Funds for Promoting Science and Technology” (S.Y.) and by a Grant-in-Aid for Scientific Research on Innovative Areas (No. 20108007, “π-Space”) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.
PY - 2010
Y1 - 2010
N2 - The "bottom-up" strategy is an attractive and promising approach for the construction of nanoarchitectures. Supramolecular assemblies based on noncovalent interactions have been explored in an attempt to control the surface properties. In this chapter, we focus on advances made in the past 5 years in the field of scanning tunneling microscopy (STM) on supramolecularly nanostructured phthalocyanines and porphyrins on single-crystal surfaces. The design of supramolecular nanoarchitectures consisting of phthalocyanines and porphyrins, supramolecular traps of C60 and coannulene, direct metallation on phthalocyanines and porphyrins adlayers, direct synthesis of porphyrin oligomers at surfaces, axial coordination of phthalocyanines and porphyrins, and nanoapplications induced by tip manipulation at surfaces were clearly visualized by STM.
AB - The "bottom-up" strategy is an attractive and promising approach for the construction of nanoarchitectures. Supramolecular assemblies based on noncovalent interactions have been explored in an attempt to control the surface properties. In this chapter, we focus on advances made in the past 5 years in the field of scanning tunneling microscopy (STM) on supramolecularly nanostructured phthalocyanines and porphyrins on single-crystal surfaces. The design of supramolecular nanoarchitectures consisting of phthalocyanines and porphyrins, supramolecular traps of C60 and coannulene, direct metallation on phthalocyanines and porphyrins adlayers, direct synthesis of porphyrin oligomers at surfaces, axial coordination of phthalocyanines and porphyrins, and nanoapplications induced by tip manipulation at surfaces were clearly visualized by STM.
KW - Metal single-crystal surface
KW - Phthalocyanines
KW - Porphyrins
KW - Scanning tunneling microscopy (STM)
KW - Supramolecular assembly
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U2 - 10.1007/978-3-642-04752-7_5
DO - 10.1007/978-3-642-04752-7_5
M3 - Chapter
AN - SCOPUS:78049353972
SN - 9783642047510
T3 - Structure and Bonding
SP - 137
EP - 168
BT - Functional Phthalocyanine Molecular Materials
A2 - Jiang, Jianzhuang
A2 - Jiang, Jianzhuang
ER -