Supported metal catalysts for total hydrogenation of furfural and 5-hydroxymethylfurfural

研究成果: Review article査読

29 被引用数 (Scopus)

抄録

Total hydrogenation of furfural and 5-hydroxymethylfurfural (HMF), both of which are important platform chemicals from biomass, produces tetrahydrofurfuryl alcohol (THFA) and 2,5-bis(hydroxymethyl)tetrahydrofuran (BHTHF), respectively, and these products can be used as solvent or raw material of resin. Ni catalysts can give good yields in these reactions; however the low activity and stability are problems. Supported monometallic Pd and Ru catalysts have been reported to be also active in hydrogenation, although the selectivity for total hydrogenation tends to be lower. Other monometallic catalysts such as Cu and Pt generally have low activity in furan ring hydrogenation of furfuryl alcohol (FOL) and 2,5-bis(hydroxymethyl)furan intermediates. We explored various multicomponent catalysts and found that Ni-Pd/SiO2, Pd-Ir/SiO2 and Rh-Ir-ReOx/SiO2 give good yield of THFA or BHTHF with much higher activity than the mixture of each component supported on SiO2.

本文言語English
ページ(範囲)1-9
ページ数9
ジャーナルJournal of The Japan Petroleum Institute
60
1
DOI
出版ステータスPublished - 2017

ASJC Scopus subject areas

  • 燃料技術
  • エネルギー工学および電力技術

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