Structure and Raman scattering of Cs3C60 under high pressure

S. Fujiki, Y. Kubozono, S. Emura, Y. Takabayashi, S. Kashino, A. Fujiwara, K. Ishii, H. Suematsu, Y. Murakami, Y. Iwasa, T. Mitani, H. Ogata

研究成果: Article査読

13 被引用数 (Scopus)


Raman scattering is studied for a pressure-induced superconductor Cs3C60 in a pressure region from 1 bar to 62 kbar. The center frequency ω0 for Hg(1) and Hg(2) Raman peaks increase by applying pressure, but the increase shows a saturation in the high-pressure region. On the other hand, the ω0 for Ag(1) and Ag(2) modes increase monotonically in all pressure regions. The electron-phonon coupling constant for Cs3C60 shows a rapid decrease up to 30 kbar and an increase above 30 kbar. This result may be associated with a transformation from a multiphase (body-centered orthorhombic and A 15 phases) to a single phase around 20 kbar. X-ray powder diffraction pattern at 11 K under a pressure of 40 kbar shows that a superconducting phase for Cs3C60 is body-centered orthorhombic.

ジャーナルPhysical Review B - Condensed Matter and Materials Physics
出版ステータスPublished - 2000 9月 1

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学


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