Structure and electronic properties of TTF bisannulated 24-crown-8 charge transfer complexes

Y. Abe, T. Akutagawa, T. Hasegawa, T. Nakamura, K. Sugiura, Y. Sakata, T. Inabe, C. A. Christensen, J. Becher

研究成果: Conference article査読

4 被引用数 (Scopus)

抄録

Charge transfer (CT) complexes of tetrathiafulvalene bisannulated 24-crown-8 (1) with tetrafluoro (F4)-, 2,5-dibromo (Br2)-, 2,5-dichloro (Cl2)-tetracyanoquinodimethane (TCNQ), and 2,3-dicyano-5,6-dichloro-p-benzoquinone (DDQ) were prepared. The electronic ground state of the acceptor varies from the completely ionic to partial charge transfer state. Within the CT complexes the donor 1 was completely oxidized to the divalent cationic state 12+. The molecular conformation of 12+ in Cl2-TCNQ complex was an intra-dimer form folded over the flexible part of macrocyclic 24-crown-8.

本文言語English
ページ(範囲)1599-1600
ページ数2
ジャーナルSynthetic Metals
102
1-3
DOI
出版ステータスPublished - 1999
外部発表はい
イベントProceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier
継続期間: 1998 7 121998 7 18

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 材料力学
  • 機械工学
  • 金属および合金
  • 材料化学

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