抄録
An attempt has been made to prepare a new proton conducting polymer electrolyte based on polyvinyl alcohol (PVA) doped with NH4NO3 by solution casting technique. The complex formation between polymer and dissociated salt has been confirmed by X-ray diffraction analysis. The ionic conductivity of the prepared polymer electrolyte has been found by ac impedance spectroscopic analysis. The highest ionic conductivity has been found to be 7.5 × 10-3 Scm-1 at ambient temperature for 20 mol% NH4NO3-doped PVA with low activation energy (~0.19 eV). The temperature-dependent conductivity of the polymer electrolyte follows an Arrhenius relationship, which shows hopping of ions in the polymer matrix.
本文言語 | English |
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ページ(範囲) | 487-491 |
ページ数 | 5 |
ジャーナル | Ionics |
巻 | 15 |
号 | 4 |
DOI | |
出版ステータス | Published - 2009 1 1 |
外部発表 | はい |
ASJC Scopus subject areas
- Chemical Engineering(all)
- Materials Science(all)
- Engineering(all)
- Physics and Astronomy(all)