Strategies for the synthesis of 2-substituted indoles and indolines starting from acyclic α-phosphoryloxy enecarbamates

Haruhiko Fuwa, Makoto Sasaki

研究成果: Article

58 引用 (Scopus)

抜粋

Strategies have been developed for the synthesis of 2-substituted indoles and indolines starting from acyclic α-phosphoryloxy enecarbamates. A highly chemoselective cross-coupling of N-(o-bromophenyl)-α- phosphoryloxyenecarbamates with boron nucleophiles enabled the efficient preparation of various N-(o-bromophenyl)enecarbamates, which served as useful precursors for subsequent Heck-type cyclization or 5-endo-trig aryl radical cyclization to furnish 2-substituted indoles or indolines, respectively.

元の言語English
ページ(範囲)3347-3350
ページ数4
ジャーナルOrganic letters
9
発行部数17
DOI
出版物ステータスPublished - 2007 8 16

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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