Stereoselective formation of a β-lactam fused oxathiazepin: A synthetic approach to eudistomins

Tohru Yamashita, Hidetoshi Tokuyama, Tohru Fukuyama

研究成果: Article査読

5 被引用数 (Scopus)

抄録

A synthetic approach to eudistomin via a β-lactam fused bicyclic oxathiazepin intermediate is described. A β-lactam fused oxathiazepin derivative was synthesized by intramolecular 7-membered oxime ether formation and subsequent face-selective reduction of the C-N double bond. A fully functionalized orthoalkenylphenylthioanilide bearing oxathiazepin ring was then prepared and construction of the indole skeleton under several radical-mediated conditions was examined.

本文言語English
ページ(範囲)738-740
ページ数3
ジャーナルSynlett
5
出版ステータスPublished - 2003 5 1
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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