抄録
A synthetic approach to eudistomin via a β-lactam fused bicyclic oxathiazepin intermediate is described. A β-lactam fused oxathiazepin derivative was synthesized by intramolecular 7-membered oxime ether formation and subsequent face-selective reduction of the C-N double bond. A fully functionalized orthoalkenylphenylthioanilide bearing oxathiazepin ring was then prepared and construction of the indole skeleton under several radical-mediated conditions was examined.
本文言語 | English |
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ページ(範囲) | 738-740 |
ページ数 | 3 |
ジャーナル | Synlett |
号 | 5 |
出版ステータス | Published - 2003 5月 1 |
外部発表 | はい |
ASJC Scopus subject areas
- 有機化学