Stepwise bromination of two acetylene molecules on a butterfly-type tetrairon core and reactivity of resulting bromoacetylene fragment toward nucleophiles

Masato Takano, Masaaki Okazaki, Hiromi Tobita

研究成果: Article査読

11 被引用数 (Scopus)

抄録

Treatment of the acetylene-coordinated tetrairon cluster, [(η5-C5H4Me)4Fe4(HCCH)2]+, with N-bromosuccinimide led to stepwise bromination of two acetylene ligands to form [(η5-C5H4Me)4Fe4(HCCBr)(HCCH)]+, [(η5-C5H4Me)4Fe4(HCCBr)2]+, [(η5-C5H4Me)4Fe4(BrCCBr)(HCCBr)]+, and [(η5-C5H4Me)4Fe4(BrCCBr)2]+. The reactivity of the bromoacetylene fragment in [(η5-C5H4Me)4Fe4(HCCBr)(HCCH)]+ toward water, pyridine, and ZnMe2 was also investigated.

本文言語English
ページ(範囲)9190-9191
ページ数2
ジャーナルJournal of the American Chemical Society
126
30
DOI
出版ステータスPublished - 2004 8 4

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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