Stable Push-Pull Disilene: Substantial Donor-Acceptor Interactions through the Si-Si Double Bond

Tomoyuki Kosai, Takeaki Iwamoto

研究成果: Article査読

33 被引用数 (Scopus)

抄録

The push-pull effect has been widely used to effectively tune -electron systems. Herein, we report the synthesis and properties of 1-amino-2-boryldisilene 1 as the first push-pull disilene. Its spectroscopic and structural features show substantial interactions between the Si - Si double bond and the amino and boryl substituents. The ∗ absorption band of 1 is remarkably red-shifted compared to that of the corresponding alkyl-substituted disilene 2. Treatment of 1 with H2 resulted in the cleavage of two molecules of H2 under concomitant formation of the corresponding trihydridodisilane and hydroborane.

本文言語English
ページ(範囲)18146-18149
ページ数4
ジャーナルJournal of the American Chemical Society
139
50
DOI
出版ステータスPublished - 2017 12月 20

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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