Stability conditions of polycyclic aromatic hydrocarbons at high pressures and temperatures

A. D. Chanyshev, K. D. Litasov, A. F. Shatskiy, J. Furukawa, E. Ohtani

研究成果: Article査読

4 被引用数 (Scopus)

抄録

The first results of study of stability of diverse polycyclic aromatic hydrocarbons at around 7 GPa and 773-1073 K are reported. Experiments were carried out in hydraulic multi-anvil presses. The run products after quenching were analyzed using a method of matrix-assisted laser desorption-ionization (MALDI). The formation of polymers of starting matters was determined at 7 GPa and 773-883 K. The polymers are characterized by atomic masses up to 5000 Da, that are multiple by masses of starting matters. At higher temperatures (873-1073 K), the selected PAHs and their polymers become unstable. The decomposition temperature of PAHs and their polymers exclude their stability under Earth's mantle conditions. The studies could be of great significance for the low-temperature near-surface geodynamics of small and large planetary bodies, which supposedly contain hydrocarbon compounds.

本文言語English
ページ(範囲)767-772
ページ数6
ジャーナルGeochemistry International
52
9
DOI
出版ステータスPublished - 2014 9

ASJC Scopus subject areas

  • 地球物理学
  • 地球化学および岩石学

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