Solvent induced reversible change of magnetic properties in a Fe(II)-Fe(III) single chain magnet

Yukihiro Kaneko, Takashi Kajiwara, Hisanori Yamane, Masahiro Yamashita

研究成果: Article査読

15 被引用数 (Scopus)

抄録

A single chain magnet (SCM), catena-[FeII(ClO4)2{FeIII(bpca)2}]ClO4 (1) includes three nitromethane molecules per a Fe(II)-Fe(III) unit as crystallized solvent which occupy the pores surrounded by four chains. Compound 1 can release or reabsorb these MeNO2 molecules like "sponges" possessing the chain structure of 1, accompanied by a reversible changing of SCM behavior during this process. Compound 1 is the first nano-magnet which shows the solvent induced reversible change of magnetic properties.

本文言語English
ページ(範囲)2074-2078
ページ数5
ジャーナルPolyhedron
26
9-11
DOI
出版ステータスPublished - 2007 6 15

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

フィンガープリント 「Solvent induced reversible change of magnetic properties in a Fe(II)-Fe(III) single chain magnet」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル