Solubility measurement of a metastable achiral crystal of sodium chlorate in solution growth

Hiromasa Niinomi, Atsushi Horio, Shunta Harada, Toru Ujihara, Hitoshi Miura, Yuki Kimura, Katsuo Tsukamoto

研究成果: Article査読

11 被引用数 (Scopus)

抄録

The solubility of the metastable achiral monoclinic phase in NaClO 3 crystallization from an aqueous solution, which appears prior to the nucleation of chiral crystals, was successfully measured in the range from 10 C to 23 C. Antisolvent crystallization method was used to obtain metastable crystals for the measurement. The solubility was determined to be about 1.6 times higher than that of the chiral stable cubic phase by observing growth or dissolution of the crystal in aqueous solution at the temperature and concentration of which is predetermined.

本文言語English
ページ(範囲)106-111
ページ数6
ジャーナルJournal of Crystal Growth
394
DOI
出版ステータスPublished - 2014 5月 15
外部発表はい

ASJC Scopus subject areas

  • 凝縮系物理学
  • 無機化学
  • 材料化学

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