Solid-state synthesis of Sn2TiO4: A new synthetic strategy for direct synthesis of sn2+ compounds using microwave irradiation

研究成果: Article査読

13 被引用数 (Scopus)

抄録

Divalent tin compound, Sn2TiO4, was synthesized by a simple solid-state reaction of component oxides under 2.45 GHz microwave irradiation. The reaction rapidly proceeds with the diffusion of hot Sn 2+ species toward TiO2 to form Sn2TiO 4 within 1 min. A drastic enhancement of reaction kinetics could be achieved under thermally nonequilibrium conditions induced by strong coupling of SnO with microwave energy. This makes it possible to avoid the disproportionation reaction of SnO to Sn and SnO2, giving us a new synthetic strategy for direct synthesis of Sn2+ compounds.

本文言語English
ページ(範囲)364-365
ページ数2
ジャーナルChemistry Letters
39
4
DOI
出版ステータスPublished - 2010 4 19

ASJC Scopus subject areas

  • Chemistry(all)

フィンガープリント 「Solid-state synthesis of Sn<sub>2</sub>TiO<sub>4</sub>: A new synthetic strategy for direct synthesis of sn<sup>2+</sup> compounds using microwave irradiation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル